- All
other stereogenic centers in the
molecules are the same in each.
Epimerization is the
interconversion of one
epimer to the
other epimer. Doxorubicin...
- of jasmine. In
racemic mixtures the odor is
floral and citrus,
while epimerized mixtures exhibit a
dense buttery-floral odor with odor
recognition thresholds...
-
dehydroxylated and
epimerized to
first component of the
gentamicin C complex,
gentamicin C2a
which then
undergoes an
epimerization by GenB2 and then a...
- (Z)-(cis)-isomers as zinc complex. The
inactive (Z)-(cis)-isomers may be
epimerized to the more
thermodynamically favored (E)-(trans)-isomers via
reflux in...
- of ring
opening occurs and the
ketose is protonated. An
example of
epimerization is
found in the
Calvin cycle when D-ribulose-5-phosphate is converted...
- For clarity, the
stereocenter on the
enolate has been
epimerized; in reality, the
opposite diastereoface of the
aldehyde would have been attacked....
-
exposure to heat in
alkaline pH conditions, 10 to 15% of the
parent LSD
epimerized to iso-LSD.
Under acidic conditions, less than 5% of the LSD was converted...
- Katsumi; Nozawa, Ayumu; Sugimoto, Akio; Kakuda,
Takami (2003). "Heat-
Epimerized Tea
Catechins Rich in
Gallocatechin Gallate and
Catechin Gallate Are More...
-
Since the
threo isomers are
energetically favored, it is easy to
epimerize out any of the
undesired erythro isomers. The drug that
contains only...
- (DKR). DKR
utilizes a
center of a
particular molecule that can be
easily epimerized so that the (R) and (S)
enantiomers can
interconvert throughout the reaction...
