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Enthalpy (/ˈɛnθəlpi/ ) is the sum of a
thermodynamic system's
internal energy and the
product of its
pressure and volume. It is a
state function in thermodynamics...
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leads to a
greater enthalpic penalty for
cavity formation. Next, a
particle of
solute must
separate from the bulk. This is
enthalpically unfavorable since...
- temperatures, and a Van 't Hoff plot was created. This
analysis showed that
enthalpically, the
water preferred to
hydrogen bond to the C-terminus, but entropically...
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Polymer Materials. Wiley-VCH. Politi, Regina; Harries,
Daniel (2010). "
Enthalpically driven peptide stabilization by
protective osmolytes". ChemComm. 46...
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effect is in fact
enthalpically driven,
whereas entropy can even be disfavorable. For many cases, the
molecular origin of this
enthalpically driven depletion...
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becomes metabolically stored as
potential energy in the form of
biochemical enthalpic bonds.
Wetland conditions such as
shallow water, high
plant productivity...
- ITC
troubleshoots this
issue easily by
deducing the
binding affinity,
enthalpic/entropic
contributions and its
binding stoichiometry.
Applying the ideas...
- reaction, if it were to proceed,
would be exothermic; that is,
methane is
enthalpically more
stable than
hydrogen gas and carbon. It is
possible to predict...
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acids by diazomethane, a
common transformation. Loss of N2 is both
enthalpically and
entropically favorable: [CH3N2]+ → [CH3]+ + N2, ΔH = −43 kcal/mol...
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acids are
stronger than hydrophobic-hydrophilic interactions, this is
enthalpically favorable. Once a
polypeptide chain is
fully folded, it is
called a...