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Enthalpy (/ˈɛnθəlpi/ ) is the sum of a
thermodynamic system's
internal energy and the
product of its
pressure and volume. It is a
state function in thermodynamics...
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effect is in fact
enthalpically driven,
whereas entropy can even be disfavorable. For many cases, the
molecular origin of this
enthalpically driven depletion...
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leads to a
greater enthalpic penalty for
cavity formation. Next, a
particle of
solute must
separate from the bulk. This is
enthalpically unfavorable since...
- temperatures, and a Van 't Hoff plot was created. This
analysis showed that
enthalpically, the
water preferred to
hydrogen bond to the C-terminus, but entropically...
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acids by diazomethane, a
common transformation. Loss of N2 is both
enthalpically and
entropically favorable: [CH3N2]+ → [CH3]+ + N2, ΔH = −43 kcal/mol...
- reaction, if it were to proceed,
would be exothermic; that is,
methane is
enthalpically more
stable than
hydrogen gas and carbon. It is
possible to predict...
- the A
value is
reduced from what
would be
predicted based purely on
enthalpic terms. Due to
these favorable entropic conditions, the
steric relevance...
- the
inner sphere are met.
Inner sphere electron transfer is
generally enthalpically more
favorable than
outer sphere electron transfer due to a
larger degree...
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coefficients can be
transformed to free
energy of
transfer which includes enthalpic and
entropic components, ΔG = ΔH - TΔS.
These components are experimentally...
-
becomes metabolically stored as
potential energy in the form of
biochemical enthalpic bonds.
Wetland conditions such as
shallow water, high
plant productivity...
