Definition of Enolization. Meaning of Enolization. Synonyms of Enolization

- 1021/ed1010932. Guthrie, J. Peter; Povar, Igor (2013). "Equilibrium constants for enolization in solution by com****tion alone". Journal of Physical Organic Chemistry...
- fragment is transformed into an isomer with a different chemical structure. Enolization is an example of isomerization, as is tautomerization. When the isomerization...
- is deprotonated with a strong base (hard enolization) or with a Lewis acid and a weak base (soft enolization). The resulting enolate attacks the activated...
- stabilization effects of the extended conjugation. This is very common in enolization reactions and can be viewed in the figure below under "Acidic Conditions...
- it becomes the dominant tautomer in strong acid or base solutions, and enolized aldehydes undergo nucleophilic attack at the α position. The formyl group...
- deprotonation. The relative acidity of the α-hydrogen is important in the enolization reactions of ketones and other carbonyl compounds. The acidity of the...
- 2-oxogulonolactone (2-keto-gulonolactone), which spontaneously undergoes enolization to form ascorbic acid. Reptiles and older orders of birds make ascorbic...
- geometry of the enolate: For ketones, most enolization conditions give Z enolates. For esters, most enolization conditions give E enolates. The addition...
- commonly used in the classic Claisen or Dieckmann condensations due to enolization of the electrophilic ester. The alkoxy portion of the ester must be a...
- leading to syn adducts, can be reliably formed using boron-mediated soft enolization: Often, a single diastereomer may be obtained by one crystallization...