Definition of Enolates. Meaning of Enolates. Synonyms of Enolates

- alcohols, aldehydes, and esters gives enolates. With strong bases, the deprotonation is quantitative. Typically enolates are generated from using lithium diisopropylamide...
- enantiomer. Lithium enolates are formed through deprotonation of a C−H bond α to the carbonyl group by an organolithium species. Lithium enolates are widely used...
- enol will instead cause anti addition. E enolates exhibit Felkin diastereoface selection, while Z enolates exhibit anti-Felkin selectivity. The general...
- Deprotonation of enolizable ketones, aldehydes, and esters gives enolates. Enolates can be trapped by the addition of electrophiles at oxygen. Silylation...
- cyclizations involving enolates. Two new descriptors need to be defined: enolendo and enolexo, which refer to whether both carbons of the enolate C-C fragment are...
- chemistry for a variety of oxidations, including alpha hydroxylation of enolates, epoxidation and aziridination of olefins, and other heteroatom transfer...
- tertiary alcohols. Esters also react readily with enolates. In the Claisen condensation, an enolate of one ester (1) will attack the carbonyl group of...
- that is used to synthesize vinyl triflates from the corresponding ketone enolates or dienolates. It was first reported in 1992 by Daniel Comins. The vinyl...
- the Michael reaction has broadened to include nucleophiles other than enolates. Some examples of nucleophiles include doubly stabilized carbon nucleophiles...
- N., & Warren, S. (2012). Making the more substituted enolate equivalent: thermodynamic enolates. In Organic chemistry (Second ed., p. 636). Oxford University...