Definition of Enolates. Meaning of Enolates. Synonyms of Enolates

- alcohols, aldehydes, and esters gives enolates. With strong bases, the deprotonation is quantitative. Typically enolates are generated from using lithium diisopropylamide...
- Deprotonation of enolizable ketones, aldehydes, and esters gives enolates. Enolates can be trapped by the addition of electrophiles at oxygen. Silylation...
- cyclizations involving enolates. Two new descriptors need to be defined: enolendo and enolexo, which refer to whether both carbons of the enolate C-C fragment are...
- chemistry for a variety of oxidations, including alpha hydroxylation of enolates, epoxidation and aziridination of olefins, and other heteroatom transfer...
- enol will instead cause anti addition. E enolates exhibit Felkin diastereoface selection, while Z enolates exhibit anti-Felkin selectivity. The general...
- vs Kinetic Product Jean d'Angelo, Tetrahedron report number 25 : Ketone enolates: regiospecific preparation and synthetic uses, Tetrahedron, Volume 32,...
- ISBN 0471264180. Paterson, I. (1988). "New Asymmetric Aldol Methodology Using Boron Enolates". Chemistry and Industry. 12. London: Paterson Group: 390–394. Nielsen...
- enantiomer. Lithium enolates are formed through deprotonation of a C−H bond α to the carbonyl group by an organolithium species. Lithium enolates are widely used...
- that is used to synthesize vinyl triflates from the corresponding ketone enolates or dienolates. It was first reported in 1992 by Daniel Comins. The vinyl...
- carbonyl carbon toward nucleophilic addition and the tendency for the enolates to add to electrophiles. Nucleophilic additions include in approximate...