Definition of Enolate. Meaning of Enolate. Synonyms of Enolate

- In organic chemistry, enolates are organic anions derived from the deprotonation of carbonyl (RR'C=O) compounds. Rarely isolated, they are widely used...
- substitution of an α-hydrogen by an electrophile through either an enol or enolate ion intermediate. Because their double bonds are electron rich, enols behave...
- Deprotonation of enolizable ketones, aldehydes, and esters gives enolates. Enolates can be trapped by the addition of electrophiles at oxygen. Silylation...
- enantiomer. Lithium enolates are formed through deprotonation of a C−H bond α to the carbonyl group by an organolithium species. Lithium enolates are widely used...
- using a lithium enolate compared to 97:3 using a dibutylboron enolate. Where the counterion determines stereoinduction strength, the enolate isomer determines...
- tertiary alcohols. Esters also react readily with enolates. In the Claisen condensation, an enolate of one ester (1) will attack the carbonyl group of...
- enolizable (have an α-proton and be able to undergo deprotonation to form the enolate anion). There are a number of different combinations of enolizable and...
- In its usual form, it involves the nucleophilic addition of a ketone enolate to an aldehyde to form a β-hydroxy ketone, or aldol (aldehyde + alcohol)...
- reaction or Michael 1,4 addition is a reaction between a Michael donor (an enolate or other nucleophile) and a Michael acceptor (usually an α,β-unsaturated...
- or ketones. Aldol addition or aldolization refers to the addition of an enolate or enolation as a nucleophile to a carbonyl moiety as an electrophile....