-
simplest molecule to
exhibit enantiomerism. It has been
proposed that the
enantiospecific interactions of one
rather than the
other may have led to amplification...
- of the R and S enantiomers. In 2001,
David E.
Nichols reported an
enantiospecific synthesis of Bromo-DragonFLY
which allowed the
individual R and S enantiomers...
- of the
thiophenyl group to give the
sulfoxide as
below proceeded enantiospecifically due to the
predefined stereochemistry of the
propargylic alcohol...
- own
specific way.
Stereospecificity towards enantiomers is
called enantiospecificity.
Nucleophilic substitution at sp3
centres can
proceed by the stereospecific...
-
Chambers JJ, Kurrasch-Orbaugh DM,
Parker MA,
Nichols DE (March 2001). "
Enantiospecific synthesis and
pharmacological evaluation of a
series of super-potent...
-
constant for ethanol. Thus,
after only a few
percent solvolysis of an
enantiospecific substrate, it
becomes racemic. The
examples in
textbooks of secondary...
- the
reaction was
shown to give the
allene with very high
levels of
enantiospecificity,
suggesting a
concerted mechanism. Similarly, in a com****tional study...
-
Deschamps JR,
Kelly ME,
Janero DR,
Cascio MG, et al. (June 2017). "
Enantiospecific Allosteric Modulation of
Cannabinoid 1 Receptor". ACS
Chemical Neuroscience...
- RB,
Bykov V,
Jacobson AE, Rice KC (February 1989). "Selective and
enantiospecific acylation of
kappa opioid receptors by (1S,2S)-trans-2-isothiocyan...
- 1002/0471264180.or030.02. ISBN 978-0-471-26418-7. Shing; et al. (1998). "
Enantiospecific Syntheses of (+)-Crotepoxide, (+)-Boesenoxide, (+)-β-Senepoxide, (+)-Pipoxide...