-
stereoisomer may not be
detectable by the
analytic methods used. An
enantioselective reaction is one in
which one
enantiomer is
formed in
preference to...
-
Enantioselective synthesis, also
called asymmetric synthesis, is a form of
chemical synthesis. It is
defined by
IUPAC as "a
chemical reaction (or reaction...
- is an
important atom-economical
method for
diastereoselective and
enantioselective C–C bond formation, and many
asymmetric variants exist In this general...
-
Enantioselective ketone reductions convert prochiral ketones into chiral, non-racemic
alcohols and are used
heavily for the
synthesis of stereodefined...
-
commonly used
include enantiomer analysis,
enantiomeric analysis, and
enantioselective analysis.
Chiral analysis includes all
analytical procedures focused...
-
Additionally detailed below are the history, mechanism, scope, and
enantioselective variants of the reaction.
Several reviews have been published. The...
- 4-position
blocks one
enantiotopic face of the substrate,
leading to
enantioselectivity. This is
demonstrated in the
following aldol-type reaction, but is...
-
Evans at
Harvard University. His
postdoctoral studies centered on
enantioselective catalysis, in particular, the
design and
development of Sn(II)-derived...
-
allyl boranes (13) As
illustrated by the Keck allylation,
catalytic enantioselective additions of
achiral allylmetal reagents to
carbonyl compounds also...
- they are
widely used for
enantioselective synthesis. They are
widely used in
asymmetric catalysis.
Modern enantioselective synthesis typically applies...
