-
among different enamine types, with a
greater reactivity offered by
ketone enamines than
their aldehyde counterparts.
Cyclic ketone enamines follow a reactivity...
-
ketone or aldehyde.
Since enamines are
generally produced from
ketones or aldehydes, this
overall process (known as the
Stork enamine synthesis) constitutes...
-
colorless liquid. It is
classified as an
enamine.
Primary and
secondary enamines tend to isomerize, but
tertiary enamines are
kinetically stable. One unusual...
- reason, it
forms a
stable chloramine. It is
commonly used to
generate enamines.
Morpholine is
widely used in
organic synthesis. For example, it is a building...
-
substrates are
dominated by alkenes.
Polar substrates include ketones,
enamines ketimines.
Alkenes that are
particularly amenable to
asymmetric hydrogenation...
- as a self-condensation of
aliphatic nitriles catalyzed by base to form
enamines. The
reaction was
discovered by
Jocelyn Field Thorpe. The Thorpe–Ziegler...
- is
widely used to
convert ketones to
enamines.
Enamines derived from
piperidine are
substrates in the
Stork enamine alkylation reaction. Upon treatment...
- pattern. Non-carbon
nucleophiles such as water, alcohols, amines, and
enamines can also
react with an α,β-unsaturated
carbonyl in a 1,4-addition. Some...
-
titanium tetrachloride. In the
Stork enamine alkylation,
secondary amines form
enamines when
exposed to ketones.
These enamines then
react (possibly enantioselectively)...
-
aldehydes toward nucleophilic addition by
formation of
enamines (e.g. used in the
Stork enamine alkylation):
International Union of Pure and
Applied Chemistry...
