-
atoms are sulfur. 1,2-
Dithiolene metal complexes are
often referred to as "metal
dithiolenes", "metallodithiolenes" or "
dithiolene complexes". Most molybdenum-...
-
attracted much
attention as dyes. They are of
academic interest because the
dithiolenes are
noninnocent ligands. The
lengths of the C-S and C-C
bonds in the...
-
example of a near-IR
photodetector based on
neutral [M(R-dmet)2] bis(1,2-
dithiolene)
metal complexes".
Inorganic Chemistry Communications. 10 (2): 191–194...
- [Fe(S2CNEt2)2](phen). 3,4-Bis(trifluoromethyl)-1,2-dithiete
reacts to give the
dithiolene complex [Fe(S2CNEt2)2](S2C2(CF3)2).
Nitric oxide and
carbon monoxide to...
-
NacNac or acac are innocent.
catecholates and
related 1,2-dioxalenes.
dithiolenes, such as
maleonitriledithiolate (see
example of [Ni(S2C2Ph2)2]n− above)...
- can also be
found in
coordination chemistry, for
example among bis(1,2-
dithiolene)
metal complexes.
Diradicals are
usually triplets. The
phrases singlet...
- Arca, M****imiliano (May 2017). "[Au(pyb-H)(mnt)]: A
novel gold(III) 1,2-
dithiolene cyclometalated complex with
antimicrobial activity (pyb-H=C-deprotonated...
-
spectroscopy and
density functional calculations on Mo(IV) and Mo(VI)=O bis-
dithiolenes:
insights into the
mechanism of oxo
transfer in DMSO
reductase and related...
- four thiolate-like
ligands provided by the two
dithiolene cofactors, the molybdopterins. The
dithiolene and cysteinyl/selenocysteinyl
ligands are redox-innocent...
- 1,2-diimine. 1,2-****timines are “non-innocent ligands”, akin to the
dithiolenes. For example,
acetylacetone (2,4-pentanedione) and a
primary alkyl- or...
