- the
dithioacetals, with the
formula R−CH(−SR')2 (symmetric
dithioacetals) or R−CH(−SR')−SR" (asymmetric
dithioacetals). The
symmetric dithioacetals are...
- "Trimethylene
Dithioacetals of Carbohydrates, Part 6: C-C
Coupling Reactions of
Dilithiated N-Acetyl-D-glucosamine
Trimethylene Dithioacetal Derivatives"...
-
chloral hydrate is used as a
reagent for the
deprotection of acetals,
dithioacetals and
tetrahydropyranyl ethers in
organic solvents. The
compound can be...
-
oxidation of
thiols to disulfides.
Claycop is also used to
convert dithioacetals to carbonyls. A
related reagent based on
montmorillonite has proven...
- Nguyen, H. D.; Chung, J. Y. L. (1984). "Cationic
cyclization of
ketene dithioacetals. A
general synthesis of pyrrolizidine, indolizidine, and quinolizidine...
- below). It also
catalyzes other reactions that
convert enol ethers,
dithioacetals, and
vinyl sulfides to olefins. "1,3-Bis(diphenylphosphino)propane Nickel(II)...
-
alkane via a
dithioacetal. The
reaction scheme is as follows: The
ketone or
aldehyde is
activated by
conversion to
cyclic dithioacetal by
reaction with...
- (CH2S)2(CHR′S) + H2O → R′CHO + ....
Trithiane is the
dithioacetal of formaldehyde.
Other dithioacetals undergo similar reactions to the above. It is also...
- Luh, Tien-Yau (1992). "Nickel-Catalyzed
Silylolefination of
Allylic Dithioacetals: (E,E)-Trimethyl(4-Phenyl-1,3-Butadienyl)Silane".
Organic Syntheses...
- acid catalysis. They
typically are
intermediates in the
formation of
dithioacetals (R−CH(S−R’)2): R − CH ( OH ) S − R ′ + R ′ − SH ↽ − − ⇀ R − CH ( S −...
