-
Disilyne is a low
valent silicon compound with the
chemical formula Si2R2
where oxidation state of Si is +1.
Several isomers are possible, but none are...
- one to use multi-reference methods.
Example Is the
bonding situation in
disilyne Si2H2 the same as in
acetylene (C2H2)? A
series of ab
initio studies of...
-
reactive compared to alkanes.
Disilene and
disilynes are
quite rare,
unlike alkenes and alkynes.
Examples of
disilynes, long
thought to be too
unstable to be...
- In this form, the
silicyne chains that link the
silicene hexagons use
disilyne bonding alternating with
disilane bonding,
analogous to polyyne. Phillip...
- spectroscopically. The
first members of each
respectively are
disilene H2Si=SiH2 and
disilyne H−Si≡Si−H, the
silicon analogues of
ethylene and
acetylene respectively...
-
silane compound is
reduced in KC8 in THF solvent. Additionally, a
dianionic disilyne (Si-Si
triple bond) was
reported in the form of a Mg complex. Two equivalents...
- 2-disilabenzene was
synthesized via
formal [2+2+2]
cyclotrimerization of a
disilyne (Si-Si
triple bonded species) and phenylacetylene. Some
theoretical studies...
- Four-Membered Ring with Non-Kekulé
Singlet Biradical Character from a
Disilyne".
Journal of the
American Chemical Society. 133 (32): 12478–12481. Bibcode:2011JAChS...
-
substituent groups,
locate the
double bond, and name the main chain.
Disilane Disilyne Organosilicon chemistry Double bond rule
Trisilaallene Philip P. Power...
-
xylene thereby releasing its
strain energy[clarification needed].
Disilane Disilyne McCarthy, M. C.; Yu, Z.; Sari, L.; Schaefer, H. F.; Thaddeus, P. (15 February...
