Definition of Disilenes. Meaning of Disilenes. Synonyms of Disilenes

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Definition of Disilenes

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Meaning of Disilenes from wikipedia

- tautomers, that are very close in energy: (μ2-H)disilene, and disilanylidene. Disilenes bearing sterically bulky substituents are isolable and have been well...
- peculiarity of disilenes is the trans-bending of the substituents, which is never observed in alkenes. The trans-bent angles of disilenes between the R2Si...
- atom overlapping with the empty p orbital on the other. In contrast, in disilenes each silicon atom has planar coordination but the substituents are twisted...
- significantly greater total enthalpy than a single silene double bond, so simple disilenes readily autopolymerise, and silicon favors the formation of linear chains...
- first stable (kinetically shielded) silene was reported in 1981 by Brook. Disilenes have Si=Si double bonds and disilynes are silicon analogues of an alkyne...
- analogues. Disilane and longer silanes are quite reactive compared to alkanes. Disilene and disilynes are quite rare, unlike alkenes and alkynes. Examples of disilynes...
- characterized spectroscopically. The first members of each respectively are disilene H2Si=SiH2 and disilyne H−Si≡Si−H, the silicon analogues of ethylene and...
- a sulfinyl group), and sulfones (R-S(=O)2-R′, the sulfonyl group) Si disilenes silylidenephosphanes a.k.a. phosphasilenes, rare silanethiones, rare,...
- Marek; Scheer, Manfred (2017). "Different Reactivity of As4 towards Disilenes and Silylenes". Angewandte Chemie International Edition. 56 (23): 6655–6659...
- Cui, Chunming (April 8, 2020). "Synthesis of Boryl-Substituted Disilane, Disilene, and Silyl Cation". Organometallics. 39 (23): 4164–4168. doi:10.1021/acs...