Definition of Disilene. Meaning of Disilene. Synonyms of Disilene

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Definition of Disilene

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Meaning of Disilene from wikipedia

- Disilene is an inorganic compound with the chemical formula Si 2H 4. The name disilene, referring to the structure of a particular prototropic tautomer...
- parent molecule is disilene, Si2H4. The first transient disilene was reported in 1972 by D. N. Roark and Garry J. D. Peddle. Simple disilenes easily polymerize...
- analogues. Disilane and longer silanes are quite reactive compared to alkanes. Disilene and disilynes are quite rare, unlike alkenes and alkynes. Examples of disilynes...
- characterized spectroscopically. The first members of each respectively are disilene H2Si=SiH2 and disilyne H−Si≡Si−H, the silicon analogues of ethylene and...
- significantly greater total enthalpy than a single silene double bond, so simple disilenes readily autopolymerise, and silicon favors the formation of linear chains...
- atom overlapping with the empty p orbital on the other. In contrast, in disilenes each silicon atom has planar coordination but the substituents are twisted...
- Cui, Chunming (April 8, 2020). "Synthesis of Boryl-Substituted Disilane, Disilene, and Silyl Cation". Organometallics. 39 (23): 4164–4168. doi:10.1021/acs...
- first stable (kinetically shielded) silene was reported in 1981 by Brook. Disilenes have Si=Si double bonds and disilynes are silicon analogues of an alkyne...
- reported in 1992 by West and coworkers, involving the reaction of As4 with a disilene compound, tetramesityldisilene, to generate a mixture of compounds including...
- of the charge on silicon. When the silylenoid is irradiated or heated a disilene forms probably via a silylene intermediate. With electrophiles it reacts...