Definition of Diradicals. Meaning of Diradicals. Synonyms of Diradicals

- organic compounds, where most diradicals are extremely reactive and non-Kekulé molecules that are rarely isolated. Diradicals are even-electron molecules...
- charge transfer. Diradicals are molecules containing two radical centers. Dioxygen (O2) is an important example of a stable diradical. Singlet oxygen,...
- and act independently as isolated radical species. Diradicals are characterized by their diradical character, commonly quantified using an indicator γ...
- dioxygen O2, which occurs widely in nature. Molecular oxygen (dioxygen) is a diradical containing two unpaired electrons, and superoxide results from the addition...
- triplet oxygen an unusual example of a stable and commonly encountered diradical: it is more stable as a triplet than a singlet. According to molecular...
- transition state energetically and structurally equivalent to a diradical, although the diradical is not usually a true intermediate (potential energy minimum)...
- commonly encountered allotrope of elemental oxygen is triplet dioxygen, a diradical. The unpaired electrons parti****te in three-electron bonding, shown here...
- classes of carbenes are singlet and triplet carbenes. Triplet carbenes are diradicals with two unpaired electrons, typically form from reactions that break...
- determined these compounds to have significantly less diradical character than traditional organic diradicals. The LUMO is the antibonding π* B-B orbital. Diphosphadiboretanes...
- mechanistically, the vinylcyclopropane rearrangement can be thought of as either a diradical-mediated two-step and/or orbital-symmetry-controlled pericyclic process...