- character,
leading these species to be more
properly designated as
diradicaloids.
Diradicaloids have
found applications in
small molecule activation, molecular...
- M. M.; Munz, D.; Guldi, D. M.,
Singlet Fission in Carbene-Derived
Diradicaloids. Angew. Chem. Int. Ed. 2020, 59, 7906-7914. doi:10.1002/anie.202001286...
- Hans-Georg; Ghadwal,
Rajendra S. (2021-01-13). "Isolation of a Ge(I)
Diradicaloid and
Dihydrogen Splitting".
Journal of the
American Chemical Society....
-
rings of any size. More recently, Clar's rule was
further extended to
diradicaloids in
their singlet state. When
drawing a Clar structure, the following...
- (RB=PR').
Compounds can
exhibit localized singlet diradical character (
diradicaloid)
between the
boron atoms in the
solution and
solid state. The
first suggested...
- (open-s**** singlet) or not
interact at all (two-doublet). Biradicaloids/
diradicaloids are a
class of
biradicals with
significant radical centre interaction...
- also
supported by com****tional work. One
transition state with a high
diradicaloid character was found.
Following the
potential energy surface of the lowest...
