Definition of Diradical. Meaning of Diradical. Synonyms of Diradical

- chemistry, a diradical is a molecular species with two electrons occupying molecular orbitals (MOs) which are degenerate. The term "diradical" is mainly...
- significantly stabilize diradical species, leading to their isolation and structural characterization. However, these modifications decrease diradical character, leading...
- is less stable than the diradical due to Hund's rule of maximum multiplicity. The relative stability of the oxygen diradical is primarily due to the spin-forbidden...
- oxygen (singlet molecular dioxygen)". doi:10.1351/goldbook.S05695 http://meta-synthesis.com/webbook/16_diradical/diradical.html[better source needed]...
- transition state energetically and structurally equivalent to a diradical, although the diradical is not usually a true intermediate (potential energy minimum)...
- synthesis of boraphosphenes (RB=PR'). Compounds can exhibit localized singlet diradical character (diradicaloid) between the boron atoms in the solution and solid...
- trapping diradical species. Mirbach et al. reported on one such reaction in which an azo compound is lysed via photolysis to form the diradical hydrocarbon...
- ground state alkene, eventually giving the triplet diradical. Spin inversion to the singlet diradical allows closure to the cyclobutane. As an alternative...
- mechanistically, the vinylcyclopropane rearrangement can be thought of as either a diradical-mediated two-step and/or orbital-symmetry-controlled pericyclic process...
- commonly encountered allotrope of elemental oxygen is triplet dioxygen, a diradical. The unpaired electrons parti****te in three-electron bonding, shown here...