-
orbitals below). The most
commonly used
dipolarophiles are
alkenes and alkynes. Heteroatom-containing
dipolarophiles such as
carbonyls and
imines can also...
-
While dipolarophiles are
typically α,β-unsaturated
carbonyl compounds,
there have been many
recent advances in
developing new
types of
dipolarophiles. When...
- with non-metal-catalyzed cycloadditions, such as the
reactions using dipolarophiles that are electron-poor
olefins or alkynes.
Although azides are not the...
-
largest HOMO
coefficient in the nitrone.
Alkynes can also
serve as
dipolarophiles in this reaction. The
rules for
predicting alkene cycloaddition products...
-
Synthesis of
Isoxazole Derivatives from
Primary Nitro Compounds and
Dipolarophiles: The Role of the Base".
European Journal of
Organic Chemistry. 2006...
- benzophenone.
Thiobenzophenone (as well as
other thioketones) is a
dipolarophiles and dienophiles. For example, it
combines with 1,3-dienes in Diels-Alder...
- reaction)
between a 1,3-dipole
diazo compound (notably diazomethane) and a
dipolarophile. When the
dipolarphile is an alkene, the
reaction product is a pyrazoline...
-
nitrile ylides are
dipolar compounds and can be
trapped by a
variety of
dipolarophiles to
yield heterocyclic compounds, e.g. pyrrolines. The
strained ring...
- Montréalones parti****te in 1,3-dipolar
cycloaddition reactions with
dipolarophiles such as imines, alkenes, and
alkynes to
respectively afford imidazoles...
-
crosslinking in the
presence of
living cells.
Norbornenes were
selected as
dipolarophiles due to
their balance between strain-promoted
reactivity and stability...
