-
generally to any
chelating ligand, it is
commonly applied to
describe diphosphine ligands, as they can
adopt a wide
range of bite angles.
Diamines form...
- Diphosphane, or
diphosphine, is an
inorganic compound with the
chemical formula P2H4. This
colourless liquid is one of
several binary phosphorus hydrides...
- Bis[(2-diphenylphosphino)phenyl] ether, also
known as DPEphos, is a wide bite
angle diphosphine ligand used in
inorganic and
organometallic chemistry. The name DPEphos...
- 2′-bis(diphenylphosphino)-1,1′-binaphthyl) is an
organophosphorus compound. This
chiral diphosphine ligand is
widely used in
asymmetric synthesis. It
consists of a pair...
-
Diphosphines,
sometimes called bisphosphanes, are
organophosphorus compounds most
commonly used as
bidentate phosphine ligands in
inorganic and organometallic...
-
compound derived from the
heterocycle xanthene. It is used as a
bidentate diphosphine ligand and is
noteworthy for
having a
particularly wide bite
angle (108°)...
-
Phosphines of a more
specialized nature are
usually prepared by
other routes.
Diphosphines are also
available in primary, secondary, and
tertiary phosphorus substituents...
-
properties of
diphosphines makes them
especially useful in
asymmetric catalysis, e.g.
Noyori asymmetric hydrogenation.
Several diphosphines have been developed...
-
phosphorus atoms and have the
formula PnHn+2. The
highly flammable gas
diphosphine (P2H4) is an
analogue of hydrazine.
Compounds with P-C and P-O-C bonds...
- one of the
first demonstrations of the
Kumada coupling using nickel diphosphine catalysts. This mild and
efficient process contrasted with
older methods...
