-
Structure of (MeC5H4)Mn(CO)(PMe3)(η2-H2SiPh2, a
sigma complex of
diphenylsilane.
Selected distances: Si-Mn = 325, H-Fe = 149, Si-H(Mn) = 177, Si-Hterminal...
- (MeC5H4)Mn(CO)2(η2-HSiPh3), J(29Si,1H) = 65 Hz
compared to 180 Hz in free
diphenylsilane. In
silyl hydride complexes, the
coupling in
about 6 Hz.
Neutron diffraction...
- 3,5,7-adamantanetetracarboxylic acid 100884-80-8 C14H16Si
dimethyl diphenylsilane 778-24-5 C14H17ClNO4PS2
dialifor 10311-84-9 C14H17F5OSi cyclohexanol...
- of alkynes,
reductive formylation of
amines with
carbon dioxide and
diphenylsilane,
hydrogenation and
dehydrogenation of N-heteroarenes in water, cycloisomerization...