- of its instability.
Beyond the
parent dioxirane,
which is
mainly of
theoretical interest, more
common dioxiranes are
dimethyldioxirane (DMD or DMDO) and...
-
Oxidation with
dioxiranes refers to the
introduction of
oxygen into
organic substrates using dioxiranes.
Dioxiranes are well
known for
epoxidations (synthesis...
- upon
treatment of
acetone with oxone.
Dioxiranes are versatile,
especially for the
epoxidation of olefins.
Dioxiranes are also
oxidize other unsaturated...
- 14
October 2015. Murray,
Robert W. (July 1989). "Chemistry of
dioxiranes. 12.
Dioxiranes".
Chemical Reviews. 89 (5): 1187–1201. doi:10.1021/cr00095a013...
- ethers.[7]
Enantioselective dioxirane oxidations may rely on chiral, non-racemic
dioxiranes, such as Shi's fructose-based
dioxirane.
Enantioselective oxidation...
-
Acetal Alcohol Alkoxy Methoxy Ether Enol
ether Epoxide Peroxy Hydroperoxy Dioxiranes Ethylenedioxy Methylenedioxy carbonyl Acyl
Acetyl Acryloyl Benzoyl Aldehyde...
-
Acetal Alcohol Alkoxy Methoxy Ether Enol
ether Epoxide Peroxy Hydroperoxy Dioxiranes Ethylenedioxy Methylenedioxy carbonyl Acyl
Acetyl Acryloyl Benzoyl Aldehyde...
-
symmetry point groups Cs, D3h, and C2v. The C2v state,
consisting of a
dioxirane, has been
shown to be the
ground state of the molecule.
Carbon trioxide...
-
Acetal Alcohol Alkoxy Methoxy Ether Enol
ether Epoxide Peroxy Hydroperoxy Dioxiranes Ethylenedioxy Methylenedioxy carbonyl Acyl
Acetyl Acryloyl Benzoyl Aldehyde...
- substituents,
oxaziridines exhibit reactivity more
similar to that of
dioxiranes than
typical oxaziridines. Notably,
perfluoroalkyloxaziridines hydroxylate...
