- In chemistry,
dioxirane (systematically
named dioxacyclopropane, also
known as
methylene peroxide or peroxymethane) is an
organic compound with formula...
-
Oxidation with
dioxiranes refers to the
introduction of
oxygen into
organic substrates using dioxiranes.
Dioxiranes are well
known for
epoxidations (synthesis...
- upon
treatment of
acetone with oxone.
Dioxiranes are versatile,
especially for the
epoxidation of olefins.
Dioxiranes are also
oxidize other unsaturated...
- fructose-derived
catalyst (1). This
reaction is
thought to
proceed via a
dioxirane intermediate,
generated from the
catalyst ketone by
oxone (pot****ium peroxymonosulfate)...
- (DMDO) is the
organic compound with the
formula (CH3)2CO2. It is the
dioxirane derived from
acetone and can be
viewed as the
monomer of
acetone peroxide...
-
formula CH2O2 (molar m****: 46.03 g/mol) may
refer to:
Dihydroxymethylidene Dioxirane, an
unstable cyclic peroxide Formic acid, an
organic acid Methylenedioxy...
-
symmetry point groups Cs, D3h, and C2v. The C2v state,
consisting of a
dioxirane, has been
shown to be the
ground state of the molecule.
Carbon trioxide...
- is a rare,
stable member of the
dioxirane family,
known for a
single oxygen-oxygen bond (O-O).
Unlike most
dioxiranes that
decompose quickly, difluorodioxirane...
- catalyst, a ketone, is
oxidized by
stoichiometric oxone to the
active dioxirane form
before proceeding in the
catalytic cycle.
Oxaziridines such as chiral...
- and
Villiger suggested a
dioxirane intermediate,
while Georg Wittig and
Gustav Pieper suggested a
peroxide with no
dioxirane formation.
Carbon attack...
