-
Diimines are
organic compounds containing two
imine (RCH=NR') groups.
Common derivatives are 1,2-
diimines and 1,3-
diimines.
These compounds are used as...
- Diimide, also
called diazene or
diimine, is a
compound having the
formula HN=NH. It
exists as two
geometric isomers, E (trans) and Z (cis). The term diazene...
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discovered in the 1980-1990s. Nickel(II) and palladium(II)
complexes of α-
diimine ligands were
known to
efficiently catalyze polymerization of alkenes. They...
- Paul J. (2018). "Synthesis and
Electronic Structure Diversity of Pyridine(
diimine)iron
Tetrazene Complexes".
Inorganic Chemistry. 57 (16): 9634–9643. doi:10...
- a
cyclic [3,3]-sigmatropic
rearrangement occurs producing a
diimine. The
resulting diimine forms a
cyclic aminoacetal (or aminal),
which under acid catalysis...
- some cases,
HNacNacs also
serve as charge-neutral 1,3-
diimine ligands.
NacNac ligands are
diimine analogues of
acetylacetonate ligands. An intermediate...
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molecules condense with the two
carbonyl groups to give a
diimine: In the
second stage, this
diimine condenses with the aldehyde: However, the
actual reaction...
- post-metallocene
catalyst designs Catalyst supported by charge-neutral alpha-
diimine ligands.
Catalyst supported by
highly electron-withdrawing substituted...
-
multiple names:
authors list (link). Mashima,
Kazushi (2020). "Redox-Active α-
Diimine Complexes of
Early Transition Metals: From
Bonding to Catalysis". Bulletin...
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horseradish peroxidase. The
resulting one-electron
oxidation product is a
diimine-diamine complex,
which causes the
solution to take on a blue colour, and...