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Vicinal difunctionalization refers to a
chemical reaction involving transformations at two
adjacent centers (most
commonly carbons). This transformation...
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arenes to
afford organothallium(III) derivatives. It is also used to
difunctionalize alkenes. For example,
alcohol solutions of this
reagent convert simple...
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carbon atoms (i.e., in a 1,2-relationship). It may
arise from
vicinal difunctionalization. For example, the
molecule 2,3-dibromobutane
carries two vicinal...
- with
Raney nickel affords butane. When
coupled with the easy 2,5-
difunctionalization of thiophene,
desulfurization provides a
route to 1,4-disubstituted...
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Richard R. (1991). "Living Ring-Opening
Metathesis Polymerization of 2,3-
Difunctionalized 7-Oxanorbornenes and 7-Oxanorbornadienes by Mo(CHCMe2R)(N-2,6-C6H3-i-Pr2)(O-t-Bu)2...
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Synthesis of 2,4-
difunctionalized tellurophenes....
- The Liebeskind–Srogl
coupling reaction is an
organic reaction forming a new carbon–carbon bond from a
thioester and a
boronic acid
using a
metal catalyst...
- Martin, R. (2021). "sp3 Bis-Organometallic
Reagents via
Catalytic 1,1-
Difunctionalization of
Unactivated Olefins".
Angewandte Chemie. 60 (21): 11740–11744...
- "Fluoroalkyl
sulfides as photoredox-active
coupling reagents for
alkene difunctionalization".
Chemical Communications. 56 (66): 9453–9456. doi:10.1039/D0CC04617E...
-
Oxytrifluoromethylation of Alkenes:
Highly Efficient and
Regioselective Difunctionalization of C=C
Bonds Mediated by
Photoredox Catalysts".
Angewandte Chemie...
