-
between a
conjugated diene and a
substituted alkene,
commonly termed the
dienophile, to form a
substituted cyclohexene derivative. It is the prototypical...
- (or DA) reaction, the
DAINV is a
cycloaddition between an electron-rich
dienophile and an electron-poor diene.
During a
DAINV reaction,
three pi-bonds are...
- reaction, a [4+2] cycloelimination. It
involves the
formation of a
diene and
dienophile from a cyclohexene. It can be
accomplished spontaneously with heat, or...
- reaction.
Ambident dienophile 57
reacts with DAPC 54 at the
cyclobutene π-bond to
produce ligand 58; in contrast, the
related ambident dienophile 59
reacts with...
-
synthesis of ring C
began with a Diels-Alder
reaction between diene 1.3 and
dienophile 1.1 in the
presence of
phenylboronic acid (1.2), which,
after addition...
- the thioether: 2 CH2CHCO2CH3 + H2S → S(CH2CH2CO2CH3)2 It is also a good
dienophile. It is an
acute toxin with an LD50 (rats, oral) of 300 mg/kg and a TLV...
-
Capture of
benzyne as
dienophile in Diels-Alder reaction....
-
reaction is
affected by the
presence of oxygen.
Anthracene also
reacts with
dienophile singlet oxygen in a [4+2]-cycloaddition (Diels–Alder reaction): Chemical...
- is a
highly reactive diene that can
scavenge unstable and short-lived
dienophiles in a Diels-Alder reaction. It is
furthermore used as a
standard reagent...
- acts as the
dienophile and
reacts with a
diene at a carbon-carbon
double bond. In Diels–Alder
reactions quinones are used as
dienophiles. Historically...
