-
between a
conjugated diene and a
substituted alkene,
commonly termed the
dienophile, to form a
substituted cyclohexene derivative. It is the prototypical...
- (or DA) reaction, the
DAINV is a
cycloaddition between an electron-rich
dienophile and an electron-poor diene.
During a
DAINV reaction,
three pi-bonds are...
- reaction.
Ambident dienophile 57
reacts with DAPC 54 at the
cyclobutene π-bond to
produce ligand 58; in contrast, the
related ambident dienophile 59
reacts with...
- reaction, a [4+2] cycloelimination. It
involves the
formation of a
diene and
dienophile from a cyclohexene. It can be
accomplished spontaneously with heat, or...
-
Capture of
benzyne as
dienophile in Diels-Alder reaction....
-
synthesis of ring C
began with a Diels-Alder
reaction between diene 1.3 and
dienophile 1.1 in the
presence of
phenylboronic acid (1.2), which,
after addition...
- and a
dienophile. The
frontier molecular orbitals produced by a
typical structural optimization are as follows: the HOMO and LUMO of the
dienophile "ethylene"...
-
carried out
either in
solution or on
polystyrene particles. DEAD is an aza-
dienophile and an
efficient dehydrogenating agent,
converting alcohols to aldehydes...
- diester, it
undergoes bromination across the
double bond, and it is a good
dienophile. The oral LD50 is 10g/kg.
Citric acid
cycle (TCA cycle)
Fumarate reductase...
-
hydrobromination of
ethyl acrylate. With dienes,
ethyl acrylate reacts as a good
dienophile in Diels–Alder
reactions e.g. with buta-1,3-diene in a [4+2] cycloaddition...
