- Diphosphines,
sometimes called bisphosphanes, are
organophosphorus compounds most
commonly used as
bidentate phosphine ligands in
inorganic and organometallic...
-
dienes to give the
chlorophospholenium ring.
Reductive coupling of the
dichlorophosphine gives the
cyclophosphine (PhP)5. B. Buchner; L. B. Lockhart, Jr. (1951)...
-
aluminium chloride, Me2NPCl2 and
ferrocene react to give
ferrocenyl dichlorophosphine,
whereas treatment with
phenyldichlorophosphine under similar conditions...
- ; Rudolph, R. W.; Parry, R. W. (1967). "Substituted Difluoro- and
Dichlorophosphines".
Inorganic Syntheses. 22: 147–156. doi:10.1002/9780470132418.ch22...
- same
general mechanism:
formation of a
phosphenium cation from a
dichlorophosphine and
aluminum trichloride,
electrophilic addition by an
alkene to the...
- ; Rudolph, R. W.; Parry, R. W. (1967). "Substituted Difluoro- and
Dichlorophosphines".
Inorganic Syntheses.
Inorganic Syntheses. Vol. 22. pp. 147–156....
- of the type Cp2M=P-R (M = Mo, W) can be
obtained by
combining aryl-
dichlorophosphines RPCl2 with [Cp2MHLi]4.
Metal clusters containing RP
substituents are...
- be
prepared by
several methods, one
involves reductive coupling of
dichlorophosphines: 5 PhPCl2 + 5 Mg → [PhP]5 + 5 MgCl2 The
structures are complicated...
