-
organometallic chemistry, a
dicarbollide is an
anion of the
formula [C2B9H11]2-.
Various isomers exist, but most
common is 1,2-
dicarbollide derived from ortho-carborane...
- framework. Most
famous are the
dicarbollide,
complexes with the
formula M2+[C2B9H11]2−,
where M
stands for metal.
Dicarbollide complexes have been investigated...
-
precursor to
dicarbollide complexes: C2B10H12 +
NaOEt + 2 EtOH → Na+C2B9H12− + H2 + B(OEt)3 Na+C2B9H12− + NaH → Na2C2B8H11 + H2
Dicarbollides (C2B8H112-)...
- Dicarbollylcobaltate(III)
anion is a
dicarbollide cluster compound containing cobaltic cation (III) as a
metal center. The dicarbollylcobaltate(III) anion...
- vertices. A well-developed
class of
metallacarboranes are
prepared from
dicarbollides,
anions of the
formula [C2B9H11]2-.
These anions function as ligands...
- Mirkin, Chad A. (June 28, 2010). "Electronic
Tuning of Nickel-Based Bis(
dicarbollide)
Redox Shuttles in Dye-Sensitized
Solar Cells". Angew. Chem. Int. Ed...
-
polyhedral cages ranging in size from 6 to 15 vertices.
Examples include bis(
dicarbollide) complexes, such as [M(C2B9H11)2]z− and [Fe(C2B9H11)2]2−, and small-carborane...
- ****ler, C. B.; Hawthorne, M. F. (1991). "Syntheses of Charge-Compensated
Dicarbollide Ligand Precursors and
Their Use in the
Preparation of
Novel Metallacarboranes"...
-
polyethylene glycol and a
cobalt carborane anion (known as
chlorinated cobalt dicarbollide). The
actinides are
extracted by CMPO, and the
diluent is a
polar aromatic...
-
motifs are also well studied, such as boranes,
carboranes and
metal dicarbollides.[citation needed] Nitrogen,
unlike its
neighbor carbon, is much less...
