Definition of Diazoalkanes. Meaning of Diazoalkanes. Synonyms of Diazoalkanes

Here you will find one or more explanations in English for the word Diazoalkanes. Also in the bottom left of the page several parts of wikipedia pages related to the word Diazoalkanes and, of course, Diazoalkanes synonyms and on the right images related to the word Diazoalkanes.

Definition of Diazoalkanes

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Meaning of Diazoalkanes from wikipedia

- the diazo group bound to a carbon atom are called diazo compounds or diazoalkanes and are described by the general structural formula R2C=N+=N−. The simplest...
- be used with primary diazoalkanes, to produce secondary α-diazo ketones. However, there are many limitations. Primary diazoalkanes undergo azo coupling...
- reaction is the reaction of aldehydes or ketones with aliphatic diazoalkanes to form homologated ketones. It was first described by Eduard Buchner...
- transition metal catalysts (typically rhodium and copper) decompose diazoalkanes to a carbene and gaseous nitrogen; such are the Bamford–Stevens reaction...
- alkenes give epoxides. MTO also catalyses the conversion of aldehydes and diazoalkanes into an alkene. A distinctive derivative of rhenium is nonahydridorhenate...
- Marmor & P. Hilbert (1971). "Reactions of dimethylphosphono-substituted diazoalkanes. (MeO)2P(O)CR transfer to olefins and 1,3-dipolar additions of (MeO)2P(O)C(N2)R"...
- nucleophilic addition of the sulfur to the metal carbene formed from the diazoalkane followed by a Stevens-like rearrangement. Doyle expanded the scope of...
- formation of polysulfur oxides: 2 S2O → "S3" + SO2 S 2O reacts with diazoalkanes to form dithiirane 1-oxides. Possible biological occurrence: Iverson...
- Horst; Dow, Alan W.; Flood, Thomas C. (1972). "Trimethylsilyl-substituted diazoalkanes I. Trimethylsilyldiazomethane". J. Organomet. Chem. 44 (2): 279–290....
- Methylrhenium trioxide also catalyses the conversion of aldehydes and diazoalkanes into an alkene, and the oxidation of amines to N-oxides with sodium percarbonate...