Definition of Diazoalkane. Meaning of Diazoalkane. Synonyms of Diazoalkane

- the diazo group bound to a carbon atom are called diazo compounds or diazoalkanes and are described by the general structural formula R2C=N+=N−. The simplest...
- The Diazoalkane 1,3-dipolar cycloaddition is a 1,3-dipolar cycloaddition (an organic reaction) between a 1,3-dipole diazo compound (notably diazomethane)...
- reaction is the reaction of aldehydes or ketones with aliphatic diazoalkanes to form homologated ketones. It was first described by Eduard Buchner...
- alkenes give epoxides. MTO also catalyses the conversion of aldehydes and diazoalkanes into an alkene. A distinctive derivative of rhenium is nonahydridorhenate...
- be used with primary diazoalkanes, to produce secondary α-diazo ketones. However, there are many limitations. Primary diazoalkanes undergo azo coupling...
- Anthony T.; Bayless, John H. (March 1969). "Influence of solvent on diazoalkane-alkanediazonium ion equilibriums in amine deaminations". Journal of the...
- reaction Demjanov rearrangement Demjanow desamination Dess–Martin oxidation Diazoalkane 1,3-dipolar cycloaddition Diazotisation DIBAL-H selective reduction Dieckmann...
- transition metal catalysts (typically rhodium and copper) decompose diazoalkanes to a carbene and gaseous nitrogen; this occurs in the Bamford–Stevens...
- (1987-08-01). "Carbene cation radicals: the kinetics of their formation from diazoalkane cation radicals and their reactions". Journal of the American Chemical...
- nucleophilic addition of the sulfur to the metal carbene formed from the diazoalkane followed by a Stevens-like rearrangement. Doyle expanded the scope of...