- the
diazo group bound to a
carbon atom are
called diazo compounds or
diazoalkanes and are
described by the
general structural formula R2C=N+=N−. The simplest...
- The
Diazoalkane 1,3-dipolar
cycloaddition is a 1,3-dipolar
cycloaddition (an
organic reaction)
between a 1,3-dipole
diazo compound (notably diazomethane)...
-
reaction is the
reaction of
aldehydes or
ketones with
aliphatic diazoalkanes to form
homologated ketones. It was
first described by
Eduard Buchner...
- be used with
primary diazoalkanes, to
produce secondary α-diazo ketones. However,
there are many limitations.
Primary diazoalkanes undergo azo coupling...
-
Anthony T.; Bayless, John H. (March 1969). "Influence of
solvent on
diazoalkane-alkanediazonium ion
equilibriums in
amine deaminations".
Journal of the...
-
alkenes give epoxides. MTO also
catalyses the
conversion of
aldehydes and
diazoalkanes into an alkene. A
distinctive derivative of
rhenium is nonahydridorhenate...
-
reaction Demjanov rearrangement Demjanow desamination Dess–Martin
oxidation Diazoalkane 1,3-dipolar
cycloaddition Diazotisation DIBAL-H
selective reduction Dieckmann...
-
transition metal catalysts (typically
rhodium and copper)
decompose diazoalkanes to a
carbene and
gaseous nitrogen; this
occurs in the Bamford–Stevens...
- (1987-08-01). "Carbene
cation radicals: the
kinetics of
their formation from
diazoalkane cation radicals and
their reactions".
Journal of the
American Chemical...
-
carbonyl ylide,
nitrile ylide,
azomethine imine,
carbonyl imine and
diazoalkane.
These dipoles add to
electrophilic alkenes readily. Electron-withdrawing...
