Definition of Diazoacetate. Meaning of Diazoacetate. Synonyms of Diazoacetate

- Ethyl diazoacetate (N=N=CHC(O)OC2H5) is a diazo compound and a reagent in organic chemistry. It was discovered by Theodor Curtius in 1883. The compound...
- itself, are explosive. A commercially relevant diazo compound is ethyl diazoacetate (N2CHCOOEt). A group of isomeric compounds with only few similar properties...
- 7-membered rings. The first step involves formation of a carbene from ethyl diazoacetate, which cyclopropanates an aromatic ring. The ring expansion occurs in...
- scope of the reaction to include other diazo compounds, such as ethyl diazoacetate, other allyl compounds, such as allyl amines and allyl halides, and use...
- Buchner ring enlargement, starts with the reaction of benzene with ethyl diazoacetate to give the corresponding norcaradiene ethyl ester, which then undergoes...
- tetraacetate is found to be especially effective. In a typical reaction ethyl diazoacetate (a well-known carbene precursor) and dirhodium tetraacetate react with...
- rearrangement Büchner–Curtius–Schlotterbeck reaction Ammonium azide Ethyl diazoacetate Hexamethylenediamine Hydrazoic acid Lead(II) azide Peptide synthesis...
- 2-dioxaphosphorinane forms a phosphite ester. (ii) Metal carbene addition (from ethyl diazoacetate and ClFeTPP) forms an ylide. (iii) A rearrangement reaction (in blue)...
- more specifically an alpha-carbonyl diazo compound. For example, ethyl diazoacetate is converted to diethyl maleate using the ruthenium catalyst...
- postulated by Eduard Buchner in 1903 in cyclopropanation studies of ethyl diazoacetate with toluene. In 1912 Hermann Staudinger also converted alkenes to cyclopropanes...