Definition of Diazoacetate. Meaning of Diazoacetate. Synonyms of Diazoacetate

- Ethyl diazoacetate (N=N=CHC(O)OC2H5) is a diazo compound and a reagent in organic chemistry. It was discovered by Theodor Curtius in 1883. The compound...
- itself, are explosive. A commercially relevant diazo compound is ethyl diazoacetate (N2CHCOOEt). A group of isomeric compounds with only few similar properties...
- 7-membered rings. The first step involves formation of a carbene from ethyl diazoacetate, which cyclopropanates an aromatic ring. The ring expansion occurs in...
- postulated by Eduard Buchner in 1903 in cyclopropanation studies of ethyl diazoacetate with toluene. In 1912 Hermann Staudinger also converted alkenes to cyclopropanes...
- Buchner ring enlargement, starts with the reaction of benzene with ethyl diazoacetate to give the corresponding norcaradiene ethyl ester, which then undergoes...
- cyclopropanation reactions in the presence of olefins. The reaction between ethyl diazoacetate (EDA) and 1 was chosen as a model reaction due to the known difficulty...
- 2-dioxaphosphorinane forms a phosphite ester. (ii) Metal carbene addition (from ethyl diazoacetate and ClFeTPP) forms an ylide. (iii) A rearrangement reaction (in blue)...
- was reported by St. Pfau and Plattner starting from indane and ethyl diazoacetate. An efficient one-pot route entails annulation of cyclopentadiene with...
- For example, diazomethane is significantly more reactive than ethyl diazoacetate, though less reactive than its higher alkyl homologs (e.g. diazoethane)...
- tetraacetate is found to be especially effective. In a typical reaction ethyl diazoacetate (a well-known carbene precursor) and dirhodium tetraacetate react with...