-
irradiation of
diazirines with
ultraviolet light leads to
carbene insertion into
various C−H, N−H, and O−H bonds. Hence,
diazirines have
grown in po****rity...
-
produced from an
extrusion reaction with a
large free
energy change.
Diazirines and
epoxides photolyze with a
tremendous release in ring
strain to carbenes...
-
photoreactive diazirine analogs to
leucine and methionine,
which are
incorporated into proteins. Upon
exposure to
ultraviolet light, the
diazirines are activated...
- orally,
among the
highest noted.
Church RF,
Kende AS,
Weiss MJ (1965). "
Diazirines. I. Some
Observations on the
Scope of the Ammonia-Hydroxylamine-O-sulfonic...
- of Amidines. I.
Synthesis of 3-Halo- and
Other Negatively Substituted Diazirines".
Journal of the
American Chemical Society. 87 (19): 4396–4397. doi:10...
-
diaziridines are
often directly oxidized (I2/NEt3) to the more
stable diazirines. They can
undergo ring
expansion reaction with
electrophilic reagents...
-
group of
isomeric compounds with only few
similar properties are the
diazirines,
where the
carbon and two
nitrogens are
linked as a ring. Four resonance...
-
mammalian GABAA receptors has been
identified by
photolabeling using a
diazirine derivative. Additionally, it was
shown that the
hyaluronan polymer present...
-
heteroatoms Heteroatoms Saturated Unsaturated 2 ×
Nitrogen Diaziridine Diazirine Nitrogen +
Oxygen Oxaziridine Oxazirine Nitrogen +
Sulfur Thiaziridine...
- such as
ketene (ethenone) (CH 2=CO),
diazomethane (linear CH 2=N 2),
diazirine (cyclic [-CH 2-N=N-]) and
diiodomethane (I-CH 2-I). The decomposition...
