Definition of Diastereotopic. Meaning of Diastereotopic. Synonyms of Diastereotopic

- relationship, such groups can be heterotopic, homotopic, enantiotopic, or diastereotopic. Homotopic groups in a chemical compound are equivalent groups. Two...
- synthesis. In derived chiral amides and esters, the methylene protons are diastereotopic. There have been efforts to schedule Propionyl chloride as a DEA List...
- ethylated compounds, the methylene protons in the ethyl substituent are diastereotopic. Chiral reagents are known to stereoselectively modify such substituents...
- geometric constraints compared to the other face the faces are called diastereotopic. The same rules that determine the stereochemistry of a stereocenter...
- accounting for rotation around the ring–metal axis, but instead there is a diastereotopic relationship as a result of being part of a chiral complex. The achiral...
- thioethers of the type S(CH2R)2 (R ≠ H), the methylene protons are diastereotopic. Examination of the NMR spectra of such complexes reveal that they undergo...
- HAHBC-CHA′HB′ presents a mirror-related pair of diastereotopic hydrogens. Indeed, molecules with diastereotopic nuclei frequently show magnetic inequivalence...
- 2°. When attached to chiral metal centers, the P-methyl groups are diastereotopic, appearing as separate doublets in the 1H NMR spectrum. The νCO of IrCl(CO)(PPh3)2...
- epoxidation may be achieved through the use of alkene starting materials with diastereotopic faces. When racemic 3-isopropylcyclohexene was subjected to DMD oxidation...
- leads to selective attack by an achiral nucleophile at one of the (now) diastereotopic carbonyl groups. (13) Enzymatic reactions are limited by the need for...