Definition of Diastereoselectivity. Meaning of Diastereoselectivity. Synonyms of Diastereoselectivity

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Definition of Diastereoselectivity

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Meaning of Diastereoselectivity from wikipedia

- galactose to be absorbed slightly faster than glucose in human body. Diastereoselectivity is the preference for the formation of one or more than one diastereomer...
- predominantly in cis configuration (91% cis). This observed cis diastereoselectivity is due to the intermediate formation of a trichlorotitanium alkoxide...
- acids can furnish various iminodicarboxylic acid derivatives. High diastereoselectivity is usually observed, and the newly formed stereocenter usually share...
- side away from the bulky t-butyl group resulting in high facial diastereoselectivity: Pinoresinol biosynthesis involved a protein called a dirigent protein...
- reactions." Torquoselectivity is not to be confused with the normal diastereoselectivity seen in pericyclic reactions, as it represents a further level of...
- products can be obtained. In the Diels-Alder cycloaddition, the endo diastereoselectivity due to secondary orbital interactions is usually observed. In 1,3-dipolar...
- takes place through a 4-membered cyclic intermediate. The trans diastereoselectivity observed results from the reversibility of the initial addition,...
- In 2013, Carreira and co-workers reported a highly enantio- and diastereoselective α-allylation of branched aldehydes. They used chiral primary amines...
- the opposite face of the chelating β-alcohol, thus determining the diastereoselectivity. This can be contrasted with the Narasaka–Prasad reduction which...
- proceeds with high facial selectivity. Diastereoselective alkylation of a pseudoephedrine amide The diastereoselectivity is believed to result from a configuration...