-
galactose to be
absorbed slightly faster than
glucose in
human body.
Diastereoselectivity is the
preference for the
formation of one or more than one diastereomer...
-
acids can
furnish various iminodicarboxylic acid derivatives. High
diastereoselectivity is
usually observed, and the
newly formed stereocenter usually share...
-
products can be obtained. In the Diels-Alder cycloaddition, the endo
diastereoselectivity due to
secondary orbital interactions is
usually observed. In 1,3-dipolar...
-
predominantly in cis
configuration (91% cis). This
observed cis
diastereoselectivity is due to the
intermediate formation of a
trichlorotitanium alkoxide...
- the
opposite face of the
chelating β-alcohol, thus
determining the
diastereoselectivity. This can be
contrasted with the Narasaka–Prasad
reduction which...
- Narasaka–Prasad reduction,
sometimes simply called Narasaka reduction, is a
diastereoselective reduction of β-hydroxy
ketones to the
corresponding syn-dialcohols...
-
proceeds with high
facial selectivity.
Diastereoselective alkylation of a
pseudoephedrine amide The
diastereoselectivity is
believed to
result from a configuration...
-
takes place through a 4-membered
cyclic intermediate. The
trans diastereoselectivity observed results from the
reversibility of the
initial addition,...
-
David A.; Tedrow,
Jason S.; Shaw,
Jared T.; Downey, C. Wade (2002). "
Diastereoselective Magnesium Halide-Catalyzed anti-Aldol
Reactions of
Chiral N-Acyloxazolidinones"...
- side away from the
bulky t-butyl
group resulting in high
facial diastereoselectivity:
Pinoresinol biosynthesis involved a
protein called a
dirigent protein...
