- The
malonic ester synthesis is a
chemical reaction where diethyl malonate or
another ester of
malonic acid is
alkylated at the
carbon alpha (directly adjacent)...
-
occur as
natural products. The
spirocyclic core is
usually prepared by
dialkylation of an
activated carbon center. The
dialkylating group is
often a 1,3-...
- PLC. P****
polymers are
obtained by step-growth
polymerization by the
dialkylation of
bisphenolate salts.
Typical is the
reaction of 4,4'-difluorobenzophenone...
-
similar to the ****ene
process in
reaction mechanism and
involves the
dialkylation of
benzene with
propene to give 1,4-diisopropylbenzene. This compound...
- (acidity, electrophilicity, etc.) of ligands. An
early example is the
dialkylation of a
nickel dithiolate: The
corresponding alkylation in the
absence of...
-
Resorcinol is
produced in
several steps from benzene,
starting with
dialkylation with
propylene to give 1,3-diisopropylbenzene.
Oxidation and Hock rearrangement...
- ****ene
process produces phenol and butanones.
Hydroquinone is
prepared by
dialkylation of
benzene with
propene to give 1,4-diisopropylbenzene. This compound...
- N-alkylhydroxylamines
proceeds usually at nitrogen. One
challenge is
dialkylation when only
monoalkylation is desired.
RNHOH + R'X → RR'NOH + HX For O-alkylation...
-
manner to
produce a
variety of DNA
damage products such as mono- and
dialkylation, inter- and
intrastrand crosslinks, and DNA-protein crosslinks. Some...
- 1-iodopropane to give
excellent yields of α-alkylated (Z)-oximes. α,α-
Dialkylation by
further alkylation in
similar way has been achieved. It is generally...
