-
shorter lengths. In
valence bond theory,
delocalization in
benzene is
represented by
resonance structures.
Delocalized electrons also
exist in the structure...
- that
simple diagrams illustrate as not
having a π bond. They
allow a
delocalization of π
electrons across all the
adjacent aligned p-orbitals. The π electrons...
- term
resonance be
abandoned in
favor of
delocalization and
resonance energy abandoned in
favor of
delocalization energy. A
resonance structure becomes a...
- C−H bond strength, are
thermodynamically stabilized due to
resonance delocalization. However,
these radicals are
kinetically transient because they can...
-
clusters is
another example of
delocalization, this time
often in three-dimensional arrangements.
Metals take the
delocalization principle to its extreme,...
- compounds.
Aromaticity can also be
considered a
manifestation of
cyclic delocalization and of resonance. This is
usually considered to be
because electrons...
-
occurs in
relatively narrow (d-)bands,
which are
poorly delocalized. Generally,
strong delocalization in a
solid due to
large overlap with
neighboring wave...
- orbitals.
Metallic bonding is thus
possible when the
number of
electrons delocalized by each atom is less than
twice the
number of
orbitals contributing to...
-
transfer (nB → σ*AH),
orbital interactions, and
quantum mechanical delocalization,
making it a resonance-****isted
interaction rather than a mere electrostatic...
-
hyperconjugation (σ-conjugation or no-bond resonance)
refers to the
delocalization of
electrons with the parti****tion of
bonds of
primarily σ-character...
