-
formula Ru(CO)5. It is a colorless, light-sensitive
liquid that
readily decarbonylates upon
standing at room temperature. It is of
academic interest as an...
- HCN in the
presence of
strong acids to give formamides,
which can be
decarbonylated. This method, the
Ritter reaction, is used
industrially to
produce tertiary...
- cir****stances,
diarylation occurs,
giving diarylcyclopropenones,
which decarbonylate to give diarylacetylenes.
These reactions are
thought to
proceed via...
-
Decarboxylated and
decarbonylated biofuels are
renewable hydrocarbon fuels produced by
converting biom****, by
either decarboxylation or decarbonylation...
- bis(trimethylsilyl) derivative. Upon
irradiation with UV light, the
disilyl compound decarbonylates.
Decomposition of the
latter by
butanol yielded deltic acid. The acid...
-
reagents Fe(CO)5 and Fe2(CO)9 are not very useful.
Ruthenium pentacarbonyl decarbonylates readily: Ru3(CO)12 + 3 CO ⇌ 3 Ru(CO)5
Carbonylation of
ruthenium trichloride...
- then be
reduced to the
tosylhydrazine derivative 2 and
furnish the
decarbonylated product analogously to the
first possibility. This
mechanism operates...
- C6H4(C(O)NH2)CO2Na + H2O The
resulting sodium salt of
phthalamic acid is
decarbonylated via a
Hofmann rearrangement of the
amide group,
induced by hypochlorite:...
- Ru(CO)5 and Os(CO)5. The
heavier two
members are unstable,
tending to
decarbonylate to give Ru3(CO)12, and Os3(CO)12. The two
other prin****l iron carbonyls...
- synthase. In the
decarbonylation pathway,
aldehydes are
produced and
decarbonylated to form alkanes, and can be
subsequently oxidized to form secondary...
