- 2-methyl-1,3-cyclohexandione: In
dearomatization reactions the
aromaticity of the
reactant is lost. In this regard, the
dearomatization is
related to hydrogenation...
-
example of
transition metal-****isted
dearomatization is the
Buchner ring expansion.
Catalytic asymmetric dearomatization reactions (CADA) are used in enantioselective...
- Ciamician-Dennstedt
rearrangement of a
pyrrole to a pyridine. The
first step
involves dearomatization. The
second step
involves aromatization....
- and/or
reduced aromatics, e.g. benzene, toluene, xylene, by
several dearomatization methods. In a do****ent that
attempts to draw more
concise distinctions...
-
organometallic chemistry. He has also
worked extensively in the area of
dearomatization, and has
developed new
chemical tools based on tungsten, osmium, rhenium...
- have been used as
electrophiles in
synthetic organic chemistry to
build dearomatized congeners called dihydropyridines, as
demonstrated in one
example from...
- PMID 12630882. Green, J. C.; Pettus, T. R. R. (2011). "An
Oxidative Dearomatization-Induced \5 + 2]
Cascade Enabling the
Syntheses of α-Cedrene, α-Pipitzol...
-
problems in this
class of
reactions are low ortho/para
selectivities and
dearomatization (the
latter is a
particularly significant problem for phenols). Enol...
-
Selectivity in Flavin-Dependent Monooxygenase-Catalyzed
Oxidative Dearomatization. ChemRxiv. Preprint. doi:10.26434/chemrxiv.7297766.v1
Baker Dockrey...
- (2022-03-14). "Modulating the
Frontier Orbitals of an
Aluminylene for
Facile Dearomatization of
Inert Arenes**".
Angewandte Chemie International Edition. 61 (12):...