- In
organic chemistry,
cyclopropanation refers to any
chemical process which generates cyclopropane ((CH2)3) rings. It is an
important process in modern...
- Simmons–Smith
reaction is
generally preferred over
other methods of
cyclopropanation,
however it can be
expensive due to the high cost of diiodomethane...
- exothermic, and
carbene generation limits reaction rate. In Simmons-Smith
cyclopropanation, the
iodomethylzinc iodide typically complexes to any
allylic hydroxy...
- Metal-catalyzed
cyclopropanations are
chemical reactions that
result in the
formation of a
cyclopropane ring from a
metal carbenoid species and an alkene...
- inter-cage C–C bond is formed:
Cyclopropanation (the
Bingel reaction) is
another common method for
functionalizing C60.
Cyclopropanation of C60
mostly occurs at...
-
required for
formation of an
organozinc reagent in the Simmons–Smith
cyclopropanation of alkenes. The
couple has been
widely applied as a
reagent in other...
- 4-addition. Many electron-withdrawing
groups have been
shown promote the
cyclopropanation including ketones, esters,
amides (the
example below involves a Weinreb...
- Cobalt(III)-carbene
radicals have
found catalytic applications in
cyclopropanation reactions, as well as in a
variety of
other catalytic radical-type...
-
perfumes to
impart honey scents.
Methyl phenyldiazoacetate,
precursor to
cyclopropanation agents, is
prepared by
treating methyl phenylacetate with p-acetamidobenzenesulfonyl...
-
group with
xenon difluoride. Also, a
reaction of
enantioselective cyclopropanation of fluoro-substituted
allylic alcohols using zinc carbenoids. Fluoroalkanes...
