-
distorted structures,
cyclophanes retain their aromaticity, as
determined by UV-vis spectroscopy. With
regards to
their reactivity,
cyclophanes often exhibit...
-
include tetrahedranes, propellanes, cubane-type clusters,
fenestranes and
cyclophanes. March's
Advanced Organic Chemistry: Reactions, Mechanisms, and Structure...
- "Surveying
macrocyclic chemistry: from
flexible crown ethers to
rigid cyclophanes".
Chemical Society Reviews. 46 (9): 2367–2650. doi:10.1039/c7cs00185a...
-
Aromatic properties are
tested to the
limit in a
class of
compounds called cyclophanes. A
special case of
aromaticity is
found in
homoaromaticity where conjugation...
-
research were the
chemistry of
medium and
large rings, the
synthesis of
cyclophanes, and the heteroquadricyclane→heteropin rearrangement, e.g. for the synthesis...
-
ether cyclophane based on para
phenylene or naphthalene. X-ray
diffraction shows that due to pi-pi
interactions the
aromatic group of the
cyclophane is held...
-
rings attached in a
unique structure.
Cylindrocyclophanes were the
first cyclophanes found in nature,
isolated from a
species of cyanobacteria, and have proven...
-
therefore convenient for use in
supramolecular systems. More
complex cyclophanes, and
cryptands can be
synthesised to
provide more
tailored recognition...
- 1021/jo501803f
Lidija Bondarenko; Ina Dix;
Heino Hinrichs;
Henning Hopf (2004). "
Cyclophanes. Part LII:1 Ethynyl[2.2]paracyclophanes – New
Building Blocks for Molecular...
- [2.2]Paracyclophane is a
cyclophane that is
applied in bio- and
materials science. It was
first synthesized by
Brown and ****hing in 1949 by pyrolyzing...
