Definition of Cyclometalation. Meaning of Cyclometalation. Synonyms of Cyclometalation

- In organometallic chemistry, a metallacycle is a derivative of a carbocyclic compound wherein a metal has replaced at least one carbon center; this is...
- facial stereochemistry, which is chiral. The complex is prepared by cyclometalation reactions of 2-phenylpyridine and iridium trichloride, as represented...
- transfer carbon-hydrogen bond activation carbometalation hydrometalation cyclometalation nucleophilic abstraction The synthesis of many organic molecules are...
- "An alternative route to highly luminescent platinum(II) complexes: cyclometalation with N=C=N-coordinating dipyridylbenzene ligands". Inorganic Chemistry...
- Clusterification Comproportionation C–C coupling C–H activation Cyanation Cyclometalation Decarbonylation Decarboxylation Dehydration Dehalogenation Dehydrogenation...
- catalysts due to its great potential in organic synthesis. In the 1960s, cyclometalation reactions including C(sp2)–H and C(sp3)–H cleavage were pioneered by...
- nickel(II) to nickel(0) to which can then coordinate two alkyne bonds. A cyclometalation step follows to the nickelcyclopentadiene intermediate and then coordination...
- activation in organic synthesis. N,N-dimethylbenzylamine undergoes cyclometalation readily by many transition metals. A semi-practical implementations...
- for this reaction. In his initial disclosure, Paul Wender proposed a cyclometalation mechanism for Rh-catalyzed VCP (5+2) cycloaddition, which is similar...
- related to ortho-metalation in the sense that it is an intramolecular cyclometalation. Tuck-in complexes derived from Cp* ligands are derivatives of tetramethylfulvene...