- In
organometallic chemistry, a
metallacycle is a
derivative of a
carbocyclic compound wherein a
metal has
replaced at
least one
carbon center; this is...
-
facial stereochemistry,
which is chiral. The
complex is
prepared by
cyclometalation reactions of 2-phenylpyridine and
iridium trichloride, as represented...
-
Chlorination Comproportionation C–C
coupling C–H
activation Cyanation Cyclometalation Decarbonylation Decarboxylation Dehydration Dehalogenation Dehydrogenation...
-
transfer carbon-hydrogen bond
activation carbometalation hydrometalation cyclometalation nucleophilic abstraction The
synthesis of many
organic molecules are...
- "An
alternative route to
highly luminescent platinum(II) complexes:
cyclometalation with N=C=N-coordinating
dipyridylbenzene ligands".
Inorganic Chemistry...
-
catalysts due to its
great potential in
organic synthesis. In the 1960s,
cyclometalation reactions including C(sp2)–H and C(sp3)–H
cleavage were
pioneered by...
- for this reaction. In his
initial disclosure, Paul
Wender proposed a
cyclometalation mechanism for Rh-catalyzed VCP (5+2) cycloaddition,
which is similar...
-
spectroelectrochemical correlation,
aromatic hydroxylation,
oxygen atom transfer,
cyclometalation, azo
anion radical stabilization and more. The
works on vanadium, manganese...
-
related to ortho-metalation in the
sense that it is an
intramolecular cyclometalation. Tuck-in
complexes derived from Cp*
ligands are
derivatives of tetramethylfulvene...
-
activation in
organic synthesis. N,N-dimethylbenzylamine
undergoes cyclometalation readily by many
transition metals. A semi-practical implementations...
