Definition of Cyclometalate. Meaning of Cyclometalate. Synonyms of Cyclometalate
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Definition of Cyclometalate
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- ligand, it has a wide cone angle of 194°. Consequently, it tends to cyclometalate when treated with metalhalides and metal acetates. Complexes of this... - especiallyefficient and general when emplo**** as a (2-aminobiphenyl)-cyclometalatedpalladiummesylateprecatalystcomplex (Buchwald's third generation... - Mark E. (2001). "Synthesis and Characterization of Phosp****scent CyclometalatedIridium Complexes". Inorganic Chemistry. 40 (7): 1704–1711. doi:10.1021/ic0008969... - Meggers, Eric (19 March 2019). "Asymmetric Photocatalysis with Bis-cyclometalatedRhodium Complexes". Accounts of Chemical Research. 52 (3): 833–847.... - reduction of WCl6 with alkalimetalreducingagents only formed the cyclometalated W(PMe3)4(η2-CH2PMe2)H. W(PMe3)6 was firstisolated in 1990 by Parkin... - ; et al. (2001). "Synthesis and Characterization of Phosp****scent CyclometalatedIridium Complexes". Inorganic Chemistry. 40 (7): 1704–1711. doi:10.1021/ic0008969... - M****imiliano (May 2017). "[Au(pyb-H)(mnt)]: A novel gold(III) 1,2-dithiolene cyclometalatedcomplex with antimicrobialactivity (pyb-H=C-deprotonated 2-benzylpyridine;... - Gene-Hsiang; Chou, Pi-Tai (2013). "Phosp****scent Ir(iii) complexes with both cyclometalate chromop****s and phosphine-silanolate ancillary: Concurrent conversion... - Thorpe-Ingold effect. Ligands that lack aryl substituents will sometimescyclometalate via activation of methyl groups, an earlyexamplebeing the internal... - R.H.; Tilset, M. (2012). "Versatile methods for preparation of new cyclometalated gold(III) complexes". Organometallics. 31 (18): 6567–6571. doi:10.1021/om300537a...