- M****
spectral interpretation is the
method emplo**** to
identify the
chemical formula,
characteristic fragment patterns and
possible fragment ions from...
- are
often classed as
group transfer reactions and cycloadditions/
cycloeliminations, respectively,
while dyotropic reactions and
group transfer reactions...
-
nonconcerted pathways.
Cyclic isodizenes in
particular readily undergo cycloelimination and
chelotropic elimination reactions. Some of
these reactions are...
-
activation energy of 41 kcal mol−1 via a
concerted pericyclic mechanism (
cycloelimination, [σ2s+σ2a]).
Linolenic acid can be
converted into its bicyclobutane...
- reaction) is the
reverse of the Diels–Alder (DA) reaction, a [4+2]
cycloelimination. It
involves the
formation of a
diene and
dienophile from a cyclohexene...
-
either of the two olefins,
followed by a retro-Diels–Alder
reaction (a
cycloelimination reaction) to form 1,2,3-triazoles and furans. The
intermediate triazolines...
-
decomposes into
ethylene and ketene. The
activation energy for this [2+2]
cycloelimination is 52 kcal/mol. The
reverse reaction, the [2+2]
cycloaddition of ketene...
-
specifically in spiropyran-based MOF photoswitches, and the
control of
cycloelimination kinetics. To
further explore photochromic behavior in solid-state materials...
-
formation of a new
alkylidene through one
round of [2+2]
cycloaddition and
cycloelimination. ****ociation and
dissociation of a
phosphine ligand also
occurs in...
-
order of 10−2 M−1•s−1.
Photoclick chemistry utilizes a
photoinduced cycloelimination to
release N2. This
generates a short-lived 1,3
nitrile imine intermediate...
