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Although some
bisamidites were
reported as
thermally unstable compounds, 2-
cyanoethyl N,N,N',N'-tetraisopropylphosphorodiamidite, the
amidite used to prepare...
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undergoes an
addition reaction at the
caprolactam nitrogen,
producing N-(2-
cyanoethyl)-caprolactam. This is then
hydrogenated to N-aminopropyl-caprolactam,...
- Tris(
cyanoethyl)phosphine is the
organophosphorus compound with the
formula P(CH2CH2CN)3. It is
white solid that is air stable,
which is
unusual for a...
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Preferred IUPAC name 3,3′-Azanediyldipropanenitrile
Other names Bis(2-
cyanoethyl)amine
Identifiers CAS
Number 111-94-4 3D
model (JSmol)
Interactive image...
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moiety in the
building block 1 (Scheme 4) and in the
product 3 with 2-
cyanoethyl group. This
precluded the
formation of
oligonucleotides branched at the...
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silicon MOSFETs Organic insulators (e.g.,
undoped trans-polyacetylene;
cyanoethyl pullulan, CEP), for organic-based FETs. For
devices of
equal current driving...
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anhydride with 3-Methylaminopropionitrile [693-05-0] (11)
gives N-(2-
Cyanoethyl)tetrahydro-N-methyl-2-furancarboxamide [72104-44-0] (12).
Catalytic hydrogenation...
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cyanoethylation entails alkylation of the
substrate with 3-chloropropionitrile.
Cyanoethyl is a
protecting group. It is
removed by
treatment with base: RNuCH2CH2CN...
- of
Michael acceptors. Thus with acrylonitrile, it
reacts to give tris(
cyanoethyl)phosphine: PH3 + 3 CH2=CHZ → P(CH2CH2Z)3 (Z is NO2, CN, or C(O)NH2) Acid...
- the
reducing agent. TCEP can be
prepared by the acid
hydrolysis of tris(
cyanoethyl)phosphine. TCEP is
often used as a
reducing agent to
break disulfide bonds...
