-
nitrogen atoms in the core of the molecule. In this sense,
corrole is very
similar to porphyrin.
Corroles can be
prepared by a two-step process,
beginning with...
-
central cavity of a
corrole. In this area he has
reported some of the
first examples of 99Tc, rhenium, osmium, platinum, and gold
corroles.
Despite their size-mismatched...
- the
central atom, but with only 6 of the 8 edge
carbons parti****ting.
Corroles (octadehydrocorrins) are
fully aromatic derivatives of corrins. Nelson...
-
coordinated to magnesium:
chlorophyll The one-carbon-shorter analogues:
corroles,
including vitamin B12,
which is
coordinated to a
cobalt Corphins, the...
- (C6H5)2P−CH2−P(C6H5)2
neutral Can bond to two
metal atoms at once,
forming dimers Corroles tetradentate Crown ethers neutral primarily for
alkali and
alkaline earth...
- with
extended pi-delocalization such as porphyrins, phthalocyanines, and
corroles and
ligands with the
generalised formulas [D-CR=CR-D]n− (D = O, S, NR’...
-
tetragonal distortion to the porphyrin, as can be seen in the DFT
image above.
Corroles are
distinct from
porphyrins in that they
contain one less
methine to bridge...
- the only
researcher who has
studied the role of
boron in
porphyrins or
corroles. In 2007,
Brothers was
named as a
Fulbright Senior Scholar. She is also...
- a
Probe of
Ligand Noninnocence in Metallocorroles: The Case of
Copper Corroles". doi:10.1021/acs.inorgchem.9b00128.s001. hdl:10037/18125.
Retrieved 2023-03-12...
- tert-butyl
hydroperoxide catalyzed by
electron deficient manganese(III)
corroles”, J. Mol. Catal., A: Chem. 2010, 332, 1-6 doi:10.1016/j.molcata.2010.09...
