- Bis(diethylamino)
chlorophosphine is an
organophosphorus compound with the
formula (Et2N)2PCl (Et = ethyl). This
colorless liquid serves as a
masked source...
- 1996 from the
addition reaction of 1,3-diphosphoniopropenide with
chlorophosphines. The
synthesis of 1,2-dihydrophosphetes by
Doxsee et al. in 1989 from...
-
amines (R2NH) form aminophosphines. For example, bis(diethylamino)
chlorophosphine, (Et2N)2PCl, is
obtained from
diethylamine and PCl3.
Thiols (RSH) form...
- (M = Li, Na, K) A more
common synthetic route involves reduction of
chlorophosphines with
hydride reagents. For example,
reduction of dichlorophenylphosphine...
-
dilithiated compound reacts with a
variety of electrophiles, e.g.
chlorophosphines, chlorosilanes, and sulfur. Base
degradation of
ortho carborane gives...
-
Diphosphine ligands can also be
prepared from
dilithiated reagents and
chlorophosphines: XLi2 + 2 ClPAr2 → X(PAr2)2 + 2 LiCl (X =
hydrocarbon backbone) This...
-
These electrophiles include S8 (to give 1,1'-ferrocenetrisulfide),
chlorophosphines, and chlorosilanes. The
diphosphine ligand 1,1'-bis(diphenylphosphino)ferrocene...
- + S → Ph2P(S)NH2 + NH4Cl Chlorodiphenylphosphine,
along with
other chlorophosphines, is used in the
synthesis of
various phosphines. A
typical route uses...
-
Chlorodiisopropylphosphine is an
organophosphorus compound with the
formula [(CH3)2CH]2PCl. It is a
colorless liquid that
reacts with
water and oxygen...
-
applicable secondary phosphine oxides,
which arise by the
hydrolysis of the
chlorophosphine. An
example is the
hydrolysis of
chlorodiphenylphosphine to give diphenylphosphine...
