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Chlorodiphenylphosphine is an
organophosphorus compound with the
formula (C6H5)2PCl,
abbreviated Ph2PCl. It is a
colourless oily
liquid with a pungent...
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chemistry and
homogeneous catalysis. It is
prepared by
treating chlorodiphenylphosphine with
vinyl Grignard reagents. King, R.
Bruce (1972). "Poly(tertiary...
- 9-dimethylxanthene with sec-butyllithium
followed by
treatment with
chlorodiphenylphosphine. Birkholz, Mandy-Nicole; Freixa, Zoraida; van Leeuwen, Piet W....
- has a
smaller bite
angle (104 vs 108°). It is
synthesized from
chlorodiphenylphosphine and DPE.
Birkholz (née Gensow), Mandy-Nicole; Freixa, Zoraida;...
- Alternatively, it may be
prepared by the
partial hydrolysis of
chlorodiphenylphosphine or diphenylphosphine.
Diphenylphosphine oxide exists in equilibrium...
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prepared via
treatment of 4-lithiophenyl-substituted
polystyrene with
chlorodiphenylphosphine (PPh2Cl). Tris(o-tolyl)phosphine Decyl(triphenyl)phosphonium Vaska's...
- available. It may be
prepared by
treating dilithioferrocene with
chlorodiphenylphosphine: Fe(C5H4Li)2 + 2 ClPPh2 → Fe(C5H4PPh2)2 + 2 LiCl The dilithiation...
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alcoholysis of
organophosphinous chlorides. For example,
treatment of
chlorodiphenylphosphine with
methanol and base
gives methyl diphenylphosphinite: ClPPh2...
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prepared by
reductive coupling, e.g.
tetraphenyldiphosphine from
chlorodiphenylphosphine: 2 ClPPh2 + 2 Na → Ph2P−PPh2 + 2 NaCl
Ultraviolet radiation decomposes...
- Å.
Tetraphenyldiphosphine is
produced by
reductive coupling of
chlorodiphenylphosphine: 2 Ph2PCl + 2 Na → Ph2P-PPh2 + 2 NaCl The
compound is used as a...
