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Chemoselectivity is the
preferential reaction of a
chemical reagent with one of two or more
different functional groups. In a
chemoselective system, a...
- pH),
shorter reaction times,
higher yields,
simplified workups, high
chemoselectivity,
tolerance of
sensitive functional groups, and a long
shelf life. However...
- situ from NaBH4 and CeCl3(H2O)7. The
Luche reduction can be
conducted chemoselectively toward ketone in the
presence of
aldehydes or
towards α,β-unsaturated...
-
sacrificial alcohol. The
advantages of the MPV
reduction lie in its high
chemoselectivity and its use of a
cheap environmentally friendly metal catalyst. MPV...
- Late-stage
functionalization (LSF) is a desired,
chemical or biochemical,
chemoselective transformation on a
complex molecule to
provide at
least one analog...
- (2005). "Addition of
Tethered Nonaromatic Carbon Nucleophiles to
Chemoselectively Activated Amides". Org. Lett. 7 (20): 4431–4. doi:10.1021/ol0516519...
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therefore distinguish between very
similar substrate molecules to be
chemoselective,
regioselective and stereospecific. Some of the
enzymes showing the...
-
couple with
chlorinated arenes. This low
reactivity is the
basis for
chemoselectivity for
nickel insertion into the C–Br bond of
bromochlorobenzene using...
- wide
range of
different types of
ketones in both a
stereoselective and
chemoselective manner.
Substrates include a
large variety of aryl-aliphatic, di-aliphatic...
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Compared to
conventional Grignard reagents, Turbo-Grignards are more
chemoselective; esters, amides, and
nitriles do not
react with the Turbo-Grignard reagent...
