- contact,
inhalation or ingestion, in part
because of
their ability to
carbonylate hemoglobin to give carboxyhemoglobin,
which prevents the
binding of oxygen...
- {CO}}}{\ce {OH}}} Alkyl, benzyl, vinyl, aryl, and
allyl halides can also be
carbonylated in the
presence carbon monoxide and
suitable catalysts such as manganese...
-
dithiocarbonate is used as a
dehydrating agent in
chemistry and as a
carbonylating agent. It can be used as a
source of a
methanethiolate (CH3S−). S,S′-Dimethyl...
- R. M.; Scott, J. H.; Sharma, A.; Yoder, H. S. Jr (2000). "Primordial
Carbonylated Iron-Sulfur
Compounds and the
Synthesis of Pyruvate". Science. 289 (5483):...
- compound.
Reactions of Ni(CO)4 with
alkyl and aryl
halides often result in
carbonylated organic products.
Vinylic halides, such as PhCH=CHBr, are
converted to...
-
James H. Scott;
Anurag Sharma;
Hatten S.
Yoder (2000-08-25). "Primordial
carbonylated iron-sulfur
compounds and the
synthesis of pyruvate". Science. 289 (5483):...
-
Madian AG,
Regnier FE (August 6, 2010). "Proteomic
Identification of
Carbonylated Proteins and
Their Oxidation Sites".
Journal of
Proteome Research. 9...
- 1002/14356007.a05_217. ISBN 978-3527306732. When
unsaturated amines are
carbonylated in the
presence of Co2(CO)8, N-alkyl
pyrrolidinones are obtained. Carbonylation...
- chlorides. As is
typical for an SN2 process, benzylic, allylic, and α-
carbonylated alkyl halides are
excellent reactants. Even
though alkyl chlorides are...
- hexacarbonyl. In reactions, pot****ium
perrhenate (KReO4) is
reduced and
carbonylated by the
chromium reagents and
undergoes [C5H5]− ligand-transfer to afford...