-
where L is a
strongly σ-donating ligand,
typically a
phosphine (
carbodiphosphoranes) or a N-heterocyclic carbene/NHC (carbodicarbenes), that stabilises...
- Neumueller, Bernhard; Petz, Wolfgang; Frenking,
Gernot (2006). "
Carbodiphosphoranes: The
Chemistry of
Divalent Carbon(0)".
Angewandte Chemie International...
-
language as "carbodicarbenes"; (R2N)2C → C0 ← C(NR2)2), the
Ramirez carbodiphosphorane (Ph3P → C0 ← PPh3), and bis(triphenylphosphine)iminium
cation (Ph3P...
-
might also be
loosely included in this category.
Phosphanes and
carbodiphosphoranes are also
strong organosuperbases.
Despite enormous proton affinity...
- Sudip; Gilliard,
Robert J. Jr. (2022). "A
Multidimensional Approach to
CarbodiphosphoraneBi****h
Coordination Chemistry: Cationization, Redox-Flexibility, and...
- ∼6 eV
Range of
Ionization Potentials among Carbenes, Ylides, and
Carbodiphosphoranes". ACS
Organic &
Inorganic Au. 3 (2): 92–95. doi:10.1021/acsorginorgau...
