Definition of Carbinolamine. Meaning of Carbinolamine. Synonyms of Carbinolamine

- In organic chemistry, a hemiaminal (also carbinolamine) is a functional group or type of chemical compound that has a hydroxyl group and an amine attached...
- an aldehyde reacting with a secondary amine to form an enamine via a carbinolamine intermediate is shown below: Even though enamines are more nucleophilic...
- oxygen atom to create a carbinolamine. In the case of a primary amine, a water molecule can be eliminated from the carbinolamine intermediate to yield an...
- "O-Debenzylation of a Pyrrolo[2,1-c][1,4]benzodiazepine in the Presence of a Carbinolamine Functionality: Synthesis of DC-81". Synthesis. 1990: 81–84. doi:10.1055/s-1990-26795...
- Pterin-4-alpha-carbinolamine dehydratase is an enzyme that in humans is encoded by the PCBD1 gene. This gene encodes pterin-4 alpha-carbinolamine dehydratase...
- Pterin-4 alpha-carbinolamine dehydratase deficiency (PCDD) is one of the known forms of tetrahydrobiopterin deficiency. This condition is ****ociated with...
- followed by stabilizing interactions at the active site. Finally, key lysine residues and the carbinolamine intermediate are shown. Based on PDB 1JCL...
- transfer of a proton from nitrogen to oxygen to a stable hemiaminal or carbinolamine. With primary amines, water is lost in an elimination reaction to an...
- experiment with a stoichiometric amount of labeled water (H218O) supported a carbinolamine mechanism. Therefore, Hajos put forward (1974) a hemiaminal intermediate...
- amine on THF attacks the free formaldehyde intermediate to make the carbinolamine intermediate. In the second case, the nucleophilic amines on THF attack...