-
metal carbido complex is a
coordination complex that
contains a
carbon atom as a ligand. They are
analogous to
metal nitrido complexes.
Carbido complexes...
- six or fewer,
carbido clusters often have
higher nuclearities.
Metal carbonyls of the iron and
cobalt triads are well
known to form
carbido derivatives...
- of
clusters that
contain interstitial carbido ligands.
These include Ru6C(CO)17 and Ru5C(CO)15.
Anionic carbido clusters are also known,
including [Ru5C(CO)14]2−...
- carbides, such as B25C.
Metal complexes containing C are
known as
metal carbido complexes. Most
common are carbon-centered
octahedral clusters, such as...
- 15-crown-5, benzo-15-crown-5, has been used to
produce anionic complexes of
carbido ligands as
their [K(benzo-15-crown-5)2]+ salts: (Ar2N)3MoCH + KCH2Ph +...
- compounds. This list does not
include cyanides, carbonyls,
cyanamides or
carbido borates,
where carbon has
bonds to
other non-metals. However,
there are...
- and
reactivity of
metal cluster compounds,
including pioneering work on
carbido and
hydrido derivatives, and pi-donor
organic molecules" 1986 Alexander...
- P(C6H5)3 → 3 Fe(CO)4(P(C6H5)3)
Heating Fe3(CO)12
gives a low
yield of the
carbido cluster Fe5(CO)15C. Such
reactions proceed via
disproportionation of CO...
-
Robert G.; Long,
Jeffrey R. (2003-09-01). "New
Routes to
Transition Metal-
Carbido Species:
Synthesis and
Characterization of the Carbon-Centered Trigonal...
